(1)加入氢氧化钠以后,溶液体积为30毫升,溶液中醋酸钠浓度=10X0.2/30=0.067摩尔/升;剩余醋酸浓度=(0.2X20-10X0.2)/30=0.067摩尔/升
CH3COOH=CH3COO-+H+
Ka=[CH3COO-]X[H+]/[CH3COOH]
1X10^-5=0.067X[H+]/0.067
[H+]=1X10^-5,PH=5
(2)加入氢氧化钠以后,溶液体积为40毫升,溶液中醋酸钠浓度=20X0.2/40=0.1摩尔/升;醋酸无剩余
CH3COO-+H2O=CH3COOH+OH-,溶液中生成的[CH3COOH]=[OH-]
K=[CH3COOH]X[OH-]/[CH3COO-],上下X[H+]后
K=[CH3COOH]X[OH-]X[H+]/[CH3COO-]XX[H+]
=Kw/Ka=10^-14/10^-5
=10^-9
即[CH3COOH]X[OH-]/[CH3COO-]=[OH-]^2/[CH3COO-]=10^-9
[OH-]^2/0.1=10^-9
[OH-]=10^-5
[H+]=Kw/10^-5=10^-9
PH=9