α1=0.001/0.1=1%=(Ka/[HA])^1/2α2=(Ka/0.5[HA])^1/2α2/α1=[(Ka/0.5[HA])^1/2]/[(Ka/[HA])^1/2]=2^1/2α2=2^1/2×α1=2^1/2×1%=1.414%PH=-lg(0.05×1.414%)=3.15