证明:(Ⅰ)∵E,F分别是AC,BC的中点,∴EF∥PB.又EF?平面PAB,AB?平面PAB,∴EF∥平面PAB.(Ⅱ)∵侧棱PA⊥底面ABC,∴PA⊥BC,又由AB⊥BC,PA∩AB=A,∴BC⊥平面PAB,∴BC⊥PB,又∵EF∥PB,∴EF⊥BC.